Chemical mechanical polishing cmp is an essential semiconductor manufacturing process because of its local and global planarization ability in fabricating highly integrated devices. Chemicalmechanical polishing is very sensitive to pattern geometry effects and may results in dishing of metal lines and erosion of dielectrics. Chemical mechanical planarization pt01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper removal process. Surface roughness was measured using surface analyzing instrument in.
Mechanical polishing, specialist in mechanical polishing. Effect of chemical mechanical polishing on surface nature of titanium. Atomistic mechanisms of chemical mechanical polishing of a cu. Chemicalmechanical polishing behavior of tantalum in. In recent years,it has been demonstrated in many works that the above relation is also valid for metals and ceramics 2,3. Cmp chemical mechanical planarization or polishing adapted from optical lens polishing methods, i. Modeling of chemical mechanical polishing at multiple scales. Mechanical polishing of aluminum alloy sheetsplates. Mechanics of the padabrasivewafer contact in chemical.
The final polishing results are affected by many factors related to the carrier structure, the polishing pad, the slurry, and the process parameters. Results from oxide cmp experiments suggest that the wafer curvature results in a nonuniform polish rate distribution across the wafer, in agreement with the simulation based on the model. Pad height pdf asperity aspect ratio dh30 20 10 0 10 f r equenc y a. However, there are a number of points that are fundamental to the mechanical polishing. The other thirty hc specimens received chemical polishing by immersing in methylmethacrylate monomer heated to 75 c 1 c for 10 s. Since the surface topography of a wafer after a cmp process step has a significant impact on wafer yield, numerous attempts. Chemical mechanical polishing cmp is a process that is used. Chemicalmechanical polishing cmpa perspective technology in fabrication of microand nanoelectronics elements, devices and systems. Mechanical grinding alone may theoretically achieve planarization but the surface damage is. We applied our original chemical mechanical polishing cmp simulator based on the tightbinding quantum chemical molecular dynamics tbqcmd method to clarify the atomistic mechanism of cmp processes on a cu111 surface polished with a sio2 abrasive grain in aqueous h2o2. Chemical mechanical planarization of electronic materials.
Much effort has been devoted to the study of cu cmp with some different mechanisms proposed 14. Metallographic polishing by mechanical methods leonard e. Mechanical polishing doesnt remove all the surface debris like electropolishing, electropolishing is an acid bath using electricity and certain chemicals that cleans the surface of the metal, usually stainless steel, to leave a polished, mirrorlike shine which is so free of burrs, vapor stains and microscopic particles that the metal is considered passivated. The laps have either a rotating or a vibrating motion, and the specimen are held by hand. Snider department of electrical engineering, university of notre dame, notre dame, indiana 46556. Cmp chemical mechanical planarization and polishing equipment. The standard amplitude is chosen so as the polishing head goes almost until. Chemical mechanical polishing cmp is a promising means of technique for removing excess copper and planarizing the surface on a global scale. Effect of ph on chemicalmechanical polishing of copper. The global chemical mechanical planarization market is projected to expand at a cagr of 8% over the forecast. Welcome to the premier industrial source for chemical mechanical polishing cmp machines. Mechanics, mechanisms and modeling of the chemical. Apr 16, 2016 chemical mechanical polishing cmp is an essential semiconductor manufacturing process because of its local and global planarization ability in fabricating highly integrated devices. Cmp chemical mechanical polishing studies show that.
A model for chemicalmechanical polishing of a material. We reveal that the oxidation of the cu111 surface mechanically induced at the friction interface is a key process in cmp. Surface roughness needs to be somewhere around 1020 angstrom ra. The combination of chemical reaction and mechanical removal in cmp is so complex that understanding the material. The effect of mechanical and chemical polishing techniques on. This stressdependent polish nonuniformity is attributed to the nonuniform pressure. The chemical mechanical polishing cmp process has emerged as a critical technique to smooth surface topography. Pad conditioning effects in chemical mechanical polishing. Impact of film morphology on chemical mechanical polishing of tungsten article pdf available in ecs journal of solid state science and technology 58. The kemcol 15 machine is ideal for chemical mechanical polishing cmp, and cerium oxide based polishing applications. The machine is based on the popular kemet 15 lapping and polishing machine, but incorporates stainless steel elements in place of painted components for longer life, and contamination free polishing. During polishing, the surface roughness decreases with time.
Ultrarapid polishing of silicon carbide sic substrates. A common misconception is that a polished surface has a mirror bright finish, however most mirror bright finishes are actually buffed. Present and future role of chemical mechanical polishing in wafer. Experimental investigation on mechanisms of silicon chemical. To examine the polishing characteristics of the manganese oxide slurry, a series of polishing experiments for oxygen free copper have been carried out by using mno 2, mn 2 o 3 and al 2 o 3 as abrasive grains and polishing properties have been discussed.
Cmp chemical mechanical planarization solutions for the integration of highk metal gate technologies. Chemical mechanical polishing or planarization is a process of smoothing surfaces with the combination of chemical and mechanical forces. Lynn fuller, professor cmp page 2 rochester institute of technology microelectronic engineering cmp chemical mechanical planarization. December 14, 2011 the dow chemical company page 5 of 7 other for slurries containing silica abrasives, there is a possibility that the crystalline form of silica may be present in small amounts. It is pointed out that known cmp models do not account for the features of chemical and mechanical mechanisms of interaction of active fluid and particles with a polished. Controlled chemical mechanical polishing of polysilicon and silicon dioxide for singleelectron device vishwanath joshi,a alexei o. The targeted goal is to achieve planarity across the wafer a maximum surface elevation difference less than 0. The slurries are intended to contain only amorphous. Recycling a slurry for reuse in chemical mechanical planarization of. By definition, cmp is a process whereby both chemical and mechanical actions complement each. Product safety assessment chemicalmechanical planarization. For several decades, chemical mechanical polishing cmp has been the most widely used planarization method in integrated circuits manufacturing.
Seeking to improve an already successful operation, a leading edge customer took into consideration its polishing process. Damascene process and chemical mechanical planarization. Chemical mechanical planarization solutions chemical mechanical planarization cmp is a polishing process, which utilizes a chemical slurry formulation and mechanical polishing process to remove unwanted conductive or dielectric materials on the silicon wafer, achieving a nearperfect flat and smooth surface upon which layers of integrated circuitry are built. Chemical mechanical planarization cmp provides the greatest degree of planarization of any known show all. Cmp polishing is very useful for minimizing both surface and subsurface damage in ceramics, semiconductor materials, and soft metals. Modeling the chemical mechanical polishing process with circuit dimensions approaching to 0. I require a reflectance of greater than 90% at 365 nm. Note that no polishing pad was attached to the polishing plate. Chemical mechanical polishing cmp cnf users cornell. The supporting information is available free of charge on the acs publications website at doi. Material product data sheet chromium oxide thermal spray. Chemical mechanical planarization or chemical mechanical polishing cmp is a process that can remove topography from silicon oxide, poly silicon and metal surfaces.
The combination of chemical reaction and mechanical removal in cmp is so complex that understanding the material removal. Polishingpadfree electrochemical mechanical polishing of. In this research, we conducted a series of experiments to investigate the mechanisms of chemical mechanical polishing cmp of silicon. Chemical mechanical planarization cabot microelectronics. As both chemical and mechanical actions affect the effectiveness of cmp, and these actions are. Mechanics, mechanisms and modeling of the chemical mechanical. The machine is based on the popular kemet 15 lapping and polishing machine, but incorporates stainless steel elements in place of painted components for. Chemical mechanical polishing for oxygen free copper with. It is observed that variation in the cu and ta removal rates is a direct result of the change in surface characteristics of the films. Almost all direct wafer bonding has been conducted between chemicalmechanically polished substrates or between thin films that were present on top of the. Pdf chemical mechanical polishing of thin film diamond. Cmp polishing chemical mechanical polishing cmp is a technique which utilizes both a mechanical abrasive with a chemical surface reactant with the material surface. Advancement in diamond polishing technology 1 10 100 1,000 10,000 1992 1995 1996 2002 2002 2002 2004 2006 2009 year ion beam hirata 15700a laser polishing tokarev 701,000a thermo chemical polishing tokura 80100a edm wang 2,00010,000a mechanical polishing hird 250400a cvduncd krauss 120200a dynamic friction iwai. Dec 12, 20 for several decades, chemical mechanical polishing cmp has been the most widely used planarization method in integrated circuits manufacturing.
Cmp chemical mechanical planarization and polishing. Intrinsic component wear component overall fit depth of contact data3 0 201 1040 30 20 10 0 10 20 30 a low b medium c high in steady state polishing, surface structure is determined by balance between restorative effect of conditioning and destructive effect. Chemical mechanical polishing slurry for amorphous ge2sb2te5. Oxide cmp 2800amin metal cmp 3500amin cmp is a process of smoothing surfaces with the combination of chemical. Product safety assessment chemical mechanical planarization cmp polishing pads product safety assessment documents are available at. Chemical mechanical polishing is very sensitive to pattern geometry effects and may results in dishing of metal lines and erosion of dielectrics. The goal of the 1st phase cmp is to remove copper layer with high efficiency. Chemical mechanical polishing cmpa perspective technology in fabrication of microand nanoelectronics elements, devices and systems. Because of the material removal by mechanical, chemical,or chemomechanical interactions in the. Division of engineering and applied sciences, harvard university, 29 oxford street, cambridge, ma 028, usa received 27 may 2003. A model for chemicalmechanical polishing of a material surface based on contact mechanics j. Chemical mechanical planarization plays an important role in manufacture of powerful and faster semiconductor devices. Surface roughness was measured using surface analyzing instrument in microns.
Chemical mechanical polish cmp is a process technology that was adapted from wafer polishing to ic fabrication and thereby enabled the semiconductor industry to extend optical lithography and. The polishing tool was a stainless steel plate with xy grid grooves width. The development of models of cmp processes remains to be the actual problem. The sixty ac specimens received mechanical and chemical polishing in the same manner. Us8920667b2 chemicalmechanical polishing composition. The companies featured in the following listing offer a comprehensive range of chemical mechanical polishing cmp machines, as well as a variety of related products and services. It can be difficult to implement dfm rules during manual inductor design. Some of the meters we build are for extremely low flow rates 0. The term mechanical polishing is frequently used to describe the various final polishing procedures involving the use of clothcovered laps and suitable polishing abrasives. This phase stops at the surface of the barrier layer. In order to enable highk metal gate technology, new chemical mechanical planarization steps or slurries are needed to meet the stringent planarity or. The cmp process uses both chemical reaction and mechanical polishing simultaneously. I am looking for a jobshop that can mechanically polish a thin aluminum disc roughly 5 inch diameter x 164 inch thick using a rotating planetary polisher such as strasbaugh or beuhler polishing station.
Cmp chemical mechanical polishing steag mecapol 460. Chemical mechanical planarization is commonly used in ultraflat surface processing in the semiconductor industry. Complex wide metal slotting, staggered slottingstriping, and via handling during manual design are time. It is thus widely adopted for planarizing interlevel dielectric silicon dioxide layers. A production chemical mechanical planarization cmp tool in a. The evolution of surface roughness in mechanical and electrochemical polishing is shown schematically in figure 1 af.
Mechanical polishing vs electropolishing the differences. It can, in a way, be thought of as a hybrid of chemical etching and free abrasive polishing. Controlled chemical mechanical polishing of polysilicon and. Mechanics of the padabrasivewafer contact in chemical mechanical polishing a dissertation presented by dincer bozkaya to the department of mechanical and industrial engineering in partial fulfillment of the requirements for the degree of doctor of philosophy in mechanical engineering northeastern university boston, massachusetts may, 2009. In this paper, removal rates of cu and ta using aqueous slurries containing alumina and silica abrasives in h 2 o 2glycine solution are studied at varying ph values. Chemical mechanical polishing with multiple polishing pads. Chemical mechanical polishing slurry for amorphous ge2sb2te5 zhitang song1,2, weili liu1,2, liangyong wang1,2 1shanghai institute of microsystem and information technology, cas, 865 changning road, shanghai 200050, pr china 2shanghai xianna electronic technology co. Using cmp, planar, smooth, and damagefree surface can be obtained. Pdf on oct 24, 2018, hong jin kim and others published abrasive for chemical mechanical polishing find, read and cite all the research. Cmp chemical mechanical planarization cabot microelectronics. In principle, cmp is a process of smoothing and planing surfaces with the combination of chemical and mechanical forces. The purpose of this study is to make clear the polishing characteristics of the manganese oxide slurry for wire material of cu. After several decades of development, it has become accepted worldwide as a mainstream process in the fabrication of planar film.
Eye or skin contact mechanical irritation is possible. Chemical mechanical planarization cmp polishing pads. Mechanical aspects of the chemical mechanical polishing. Atomistic mechanisms of chemical mechanical polishing of a. The laps have either a rotating or a vibrating motion, and the specimen are held by hand, held mechanically, or merely confined within the polishing area. With this technique, global or nearglobal planarization can be achieved because the cmp process removes elevated features without much removal of lower areas, thus planarizing the topography plummer et al 2000. Microelectronic applications of chemical mechanical planarization. Impact of film morphology on chemical mechanical polishing.
This document is intended to introduce the techniques of chemical mechanical polishing cmp to the new user so that they may be better prepared to integrate cmp into their process flow. Cmp since that was the purpose for which it was created. It is used to planarize oxide, poly silicon or metal layers in order to prepare them for the following lithographic step, avoiding depth focus problems during illumination of. Chemical mechanical polishing cmp this feature is not available right now. The effect of mechanical and chemical polishing techniques. The polishing characteristics were evaluated using a singlesided polishing machine fact200, nano factor co. Additionally, new materials such as cu and w, introduced in ulsi fabrication, also require extensive use of the cmp process to form inlaid interconnect structures. Mechanical grinding alone causes too much surface damage, while wet. Controlled chemical mechanical polishing of polysilicon. The invention provides a chemicalmechanical polishing composition and a. Chemical mechanical polishing, or cmp, has become part of mainstream processing method in ic manufacturing. Pdf abrasive for chemical mechanical polishing researchgate.
It can be thought of as a hybrid of chemical etching and free abrasive polishing. Generating an epub file may take a long time, please be patient. Chemical mechanical polishing slurry for amorphous. Chemical mechanical planarization for microelectronics applications. Chemical mechanical planarization is a process of smoothing and planing surfaces with the combination of chemical and mechanical forces, a hybrid of chemical etching and free abrasive polishing. Chemicalmechanical planarization cmp slurries created. Some mechanical models of chemicalmechanical polishing. Chemical mechanical planarization of electronic materials by fnu atiquzzaman a thesis submitted in partial fulfillment of the requirements for the degree of master of science department of mechanical engineering college of engineering university of south florida comajor professor. Surface chemical compositions were also evaluated through fourier.
A common misconception is that a polished surface has a mirror bright finish, however most. Pdf polishing, the most expensive machining processes, in terms time and labor costs depending on the required surface finish, optic size. I work for a company that builds flowmeters for water and various gases. Lecture 30 che 323 chemical mechanical polishing cmp. Chemical mechanical polishing cmp technology is extensively used in the global planarization of highly valueadded and large components in the aerospace industry. Through implementation of chemical mechanical polishing cmp. Seeking mechanical table polishing of aluminum may 27, 2008. Hardness compressibility corrosion resistance use of chemicals to remove adhesive residues mechanical padpullers are becoming a requirement in factories polishing pad life frequency of changing pads as a function of pad life.
Chemical mechanical polishing cmp is the planarization method that has. Moreover, cmp is a critical process for fabricating the cu damascene patterns, lowk dielectrics, and shallow isolated trenches. Chemical mechanical polish for nanotechnology request pdf. Since the surface topography of a wafer after a cmp process step has a significant.
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